Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Intermediate to Long-term Estimation of Strong Earthquake Risk Areas in the Chinese Mainland Based on Geodesic Measurements     

Zhang Jing  Zhu Yiqing  Wu Yanqiang  Zhang Xi  Yang Guohua 《中国地震研究》2018,32(2):153-172

Based on previous research results, present-day crustal deformation and gravity fields in the Chinese mainland are analyzed using the GPS data, leveling, gravity and cross-fault deformations. We analyzed strain accumulation of the major faults, and identified locked or high strain accumulation segments. Combining the effects of large earthquakes in the study area, the long-term (decade) probability of large earthquakes in the Chinese mainland is estimated.  相似文献   

Coordinative similitude law considering fluid‐structure interaction for underwater shaking table tests     

Zhong‐Xian Li  Kun Wu  Yundong Shi  Ning Li  Yang Ding 《地震工程与结构动力学》2018,47(11):2315-2332

Generally, when a model is made of the same material as the prototype in shaking table tests, the equivalent material density of the scaled model is greater than that of the prototype because mass is added to the model to satisfy similitude criteria. When the water environment is modeled in underwater shaking table tests, however, it is difficult to change the density of water. The differences in the density similitude ratios of specimen materials and water can affect the similitude ratios of the hydrodynamic and wave forces with those of other forces. To solve this problem, a coordinative similitude law is proposed for underwater shaking table tests by adjusting the width of the upstream face of the model or the wave height in the model test to match the similitude ratios of hydrodynamic and wave forces with those of other forces. The designs of the similitude relations were investigated for earthquake excitation, wave excitation, and combined earthquake and wave excitation conditions. Series of numerical simulations and underwater shaking table tests were performed to validate the proposed coordinative similitude law through a comparison of coordinative model and conventional model designed based on the coordinative similitude law and traditional artificial mass simulation, respectively. The results show that the relative error was less than 10% for the coordinative model, whereas it reached 80% for the conventional model. The coordinative similitude law can better reproduce the dynamic responses of the prototype, and thus, this similitude law can be used in underwater shaking table tests.  相似文献   

Efficient Modeling of Gravity Fields Caused by Sources with Arbitrary Geometry and Arbitrary Density Distribution     

Leyuan Wu 《Surveys in Geophysics》2018,39(3):401-434

We present a brief review of gravity forward algorithms in Cartesian coordinate system, including both space-domain and Fourier-domain approaches, after which we introduce a truly general and efficient algorithm, namely the convolution-type Gauss fast Fourier transform (Conv-Gauss-FFT) algorithm, for 2D and 3D modeling of gravity potential and its derivatives due to sources with arbitrary geometry and arbitrary density distribution which are defined either by discrete or by continuous functions. The Conv-Gauss-FFT algorithm is based on the combined use of a hybrid rectangle-Gaussian grid and the fast Fourier transform (FFT) algorithm. Since the gravity forward problem in Cartesian coordinate system can be expressed as continuous convolution-type integrals, we first approximate the continuous convolution by a weighted sum of a series of shifted discrete convolutions, and then each shifted discrete convolution, which is essentially a Toeplitz system, is calculated efficiently and accurately by combining circulant embedding with the FFT algorithm. Synthetic and real model tests show that the Conv-Gauss-FFT algorithm can obtain high-precision forward results very efficiently for almost any practical model, and it works especially well for complex 3D models when gravity fields on large 3D regular grids are needed.  相似文献   

Small‐area patch‐merging method accounting for both local constraints and the overall area balance     

Chengming Li  Yong Yin  Zhaoxin Dai  Wei Wu 《Transactions in GIS》2020,24(4):1098-1118

Small‐area patch merging is a common operation in land use data generalization. However, existing research on small‐area patch merging has mainly focused on local compatibility measures, which often lead to area imbalances among land use types from a global perspective. To address the shortcomings of previous studies by resolving local and global concerns simultaneously, this article proposes a merging method that considers both local constraints and the overall area balance. First, a local optimization model that considers three constraints—namely, the areas of neighboring patches, the lengths of shared arcs, and semantic similarity—is established. The areas of small patches are first pre‐allocated. Subsequently, in accordance with an area change threshold for individual land use types, land use types with area changes that exceed this threshold are identified. The patches corresponding to these land use types are subjected to iterative adjustments while considering the overall area balance. Based on their area splitting abilities, the split lines for small‐area patches are determined, and small‐area patches are merged. Finally, actual data from Guangdong Province are used for validation. The experimental results demonstrate that the proposed method is capable of preserving the local compatibility of patches while balancing the overall area associated with each land use type.  相似文献   

南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理^*          下载免费PDF全文

石思思  吴朝东  梁金强  王熠哲  叶云涛  方允鑫  马健  翟俪娜 《古地理学报》2020,22(1):175-192

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   

国外无人反水雷特点及关键技术分析     

王久法  吴乔  高频  仝志永 《数字海洋与水下攻防》2020,3(5):382-386

许多国家将水雷视为一种重要的水中兵器，用于封锁对手、对抗强敌。针对现有反水雷装备存在的危险性高、部署速度慢、作战效率低等问题，国外海军将无人技术为代表的高新技术应用到反水雷领域，推出了多种新概念无人反水雷装备，综合运用猎、扫等多种手段，构建空中、水面、水下立体的无人反水雷装备体系，实现快速、安全、高效的反水雷作战能力，对未来反水雷作战产生重大影响。  相似文献   

An experimental approach for determination of the Weibull homogeneity index of rock or rock-like materials     

Pan  Xiaohua  Guo  Wei  Wu  Shifan  Chu  Jian 《Acta Geotechnica》2020,15(2):375-391

Acta Geotechnica - The spatial variation of the physical–mechanical properties of rock or rock-like materials is an intrinsic characteristic of the materials induced by multiscale material...  相似文献   

Effect of a nodular segment on the dynamic response of a tubular pile subjected to longitudinal vibration     

Wu  Jun-tao  Wang  Kui-hua  Liu  Xin 《Acta Geotechnica》2020,15(10):2925-2940

Acta Geotechnica - This paper investigates the effect of a nodular segment, commonly found in nodular piles, on the dynamic response of a vertical vibrating tubular pile. A developed model of a...  相似文献   

长江感潮河段潮波传播变化特征及影响因素分析     

黄竞争  张先毅  吴峥  刘锋  蔡华阳  杨清书 《海洋学报》2020,42(3):25-35

径潮相互作用是感潮河段水动力变化的典型特征，受其影响潮波传播具有明显的洪枯季及沿程变化。本文基于长江感潮河段天生港、江阴、镇江、南京、马鞍山及芜湖6个潮位站2002?2014年连续高低潮位资料及大通站月均流量数据，统计分析长江感潮河段潮波振幅衰减率、潮波传播速度及余水位坡度等传播特征值的洪枯季及沿程变化特征，并探讨这些潮波传播特征的变化规律及其主要影响因素。结果表明，潮波传播特征的洪枯季差异自上游至下游逐渐减小，其分界点位于天生港与江阴之间（其中，天生港和江阴站的多年平均洪枯季潮差差值约为0.01 m和?0.04 m）；径流动力对潮波衰减的影响主要位于江阴以上河段，江阴以下河段主要受潮汐动力控制；径流驱动下余水位坡度引起的余水位及水深增加，导致潮波传播的有效摩擦减小，当流量超过某个阈值时潮波振幅衰减反而减弱，特别是上游马鞍山-芜湖段最为明显，统计结果表明该河段流量阈值约为33 000 m3/s。本文分析结果作为前人研究的重要补充，可为长江河口感潮河段径潮相互作用机制研究及河口治理等提供基础参考。  相似文献